Vysya College of Education was established in 2007 by Vasavi Vidya Trust, a charitable trust formed with the noble objective of providing value-based and quality teacher education to students in Salem District and the surrounding areas. Since its establishment, the college has been dedicated to developing competent, responsible, and socially committed teachers through quality academic programmes and a supportive learning environment. The institution has progressed steadily through the committed efforts of its Chairman, Thiru. P. Sivanantham, and the dedicated faculty and staff. The college was affiliated to Periyar University, Salem, in 2007 and, since 2008, has been affiliated to Tamil Nadu Teachers Education University, Chennai.

Situated at Masinaickenpatty, Ayodhiyapattinam, the college enjoys a peaceful, serene, and pollution-free environment that supports effective teaching and learning. The campus includes academic and administrative buildings, computer laboratories, playground facilities, canteen, students' hostel, and other infrastructure necessary for the overall development of student-teachers. The institution continues to strive towards academic excellence, professional development, ethical values, and holistic education, preparing future teachers to meet the changing needs of society.